HOx budgets in a deciduous forest: results from the PROPHET summer 1998 campaign

TitleHOx budgets in a deciduous forest: results from the PROPHET summer 1998 campaign
Publication TypeJournal Article
Year of Publication2001
AuthorsTan D, Faloona I, Simpas J.B, Brune WH, Shepson PB, Couch TL, Sumner ALouise, Carroll MAnne, Thornberry TDean, Apel EC, Riemer DD, Stockwell WR
JournalJournal of Geophysical Research
Volume106
IssueD20
Pagination24,407-24,427
KeywordsVOLATILE ORGANIC COMPOUNDS
Abstract

Results from a tightly constrained photochemical point model for OH and HO2 are compared to OH and HO2 data collected during the Program for Research on Oxidants: Photochemistry, Emissions, and Transport (PROPHET) summer 1998 intensive campaign held in northern Michgian. The PROPHET campaign was located in a deciduous forest marked by relatively low NOx levels and high isoprene emissions. Detailed HOx budgets are presented. The model is generally unable to match the measured OH, with the observations 2.7 times greater than the model on average. The model HO2, however, is in good agreement with the measured HO2. Even with an additional postulated OH source from the ozonolysis of unmeasured terpenes, the measured OH is 1.5 times greater than the model; the model HO2 with this added source is 15% to 30% higher than the measured HO2. Moreover, the HO2/OH ratios as modeled are 2.5 to 4 times higher than the measured ratios, indicating that the cycling between OH and HO2 is poorly described by this model. We discuss possible reasons for the discrepancies.