Investigation of the nighttime decay of isoprene

TitleInvestigation of the nighttime decay of isoprene
Publication TypeJournal Article
Year of Publication2001
AuthorsHurst JM, Jr. DJBarket, Herrera-Gomez O, Couch TL, Shepson PB, Faloona I, Tan D, Brune WH, Westberg HH, Lamb BK, Biesenthal T., Young V, Goldstein A, J. Munger W, Thornberry TDean, Carroll MAnne
JournalJournal of Geophysical Research
Volume106
IssueD20
Pagination24,335-24,346
KeywordsVOLATILE ORGANIC COMPOUNDS
Abstract

A rapid nighttime decay of isoprene (2-methyl-1,3-butadiene) has been observed at several forest sites. Data from the Program for Research on Oxidants: PHotochemistry, Emissions, and Transport (PROPHET) have been carefully examined with respect to this phenomenon. Essentially every evening (at PROPHET), isoprene concentrations fall from several ppb to levels below 100 ppt, with an average lifetime of 2.7 hours. Since this decay rate exceeds that exepcted from established nighttime chemistry, other possible mechanisms are suggested and discussed. Reaction with ozone will not occur at a rate consistent with the observed decay. Calculations of nitrate radical concentrations reveal that this oxidant only becomes an important sink for isoprene after the majority of the isoprene decay has taken place. The isoprene flux data were not consistent with dry deposition playing a significant role in nighttime forest loss. On the basis of ambient measurements of OH radical concentrations at the PROPHET site, calculated isoprene decay rates were compared with observations. For some nights the observed decay can be fit strictly by OH consumption; however, the reported OH data overpredict the isoprene loss rate on most nights. We estimate that vertical mixing with isoprene-depleted air probably contributes to the fast isoprene decay observed; however, the measurements needed to support this suggestions have yet to be made.